Posted purchase request has no order number showing against it

First of all, please ensure that the corresponding Purchase Order that was created in Access Financials still exists and has not been deleted. If it has been deleted, then it is correct that there is no order number against the Purchase Request anymore and a new Purchase Request will need to be raised.
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If you are sure that the order still exists in Access Financials - our support team will need to investigate, run scripts or liaise with the hosting or development teams. Any Issues with contacting us, please see the following Get support in Financial Operations.