This is done within Financials with the following steps
Click on Purchasing tab.
Click on Settings.
Click Purchase Request Permissions.
Select the Purchase Request type in question.
Click Edit.
Click required options for the user
Click Save
This is done within Financials with the following steps
Click on Purchasing tab.
Click on Settings.
Click Purchase Request Permissions.
Select the Purchase Request type in question.
Click Edit.
Click required options for the user
Click Save